Computational 11 state |11⟩ is the product of two excited state qubits. It is a separable (unentangled) state and an eigenstate of both Z₁ and Z₂ operators with eigenvalue -1.
$$|11\rangle = |1\rangle_1 \otimes |1\rangle_2 = \begin{pmatrix} 0 \\ 0 \\ 0 \\ 1 \end{pmatrix}$$
in the computational basis ordering (|00⟩, |01⟩, |10⟩, |11⟩).
Prepare by:
Measuring |11⟩ in the computational (Z) basis always yields outcome 11. Measuring in other bases (X or Y) requires rotating both qubits first.