Computational 01 state |01⟩ is a product state with the first qubit in ground state and the second qubit in excited state. It is separable (unentangled) and an eigenstate of both Z₁ and Z₂ operators with eigenvalues +1 and -1 respectively.
$$|01\rangle = |0\rangle_1 \otimes |1\rangle_2 = \begin{pmatrix} 0 \\ 1 \\ 0 \\ 0 \end{pmatrix}$$
in the computational basis ordering (|00⟩, |01⟩, |10⟩, |11⟩).
Prepare by:
Measuring |01⟩ in the computational (Z) basis always yields outcome 01. Measuring either qubit in X or Y basis requires rotation before measurement.