von-neumann-equation
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| von-neumann-equation [June 09, 2026 at 14:38] – Ivan Janevski | von-neumann-equation [June 10, 2026 at 23:55] (current) – external edit 127.0.0.1 | ||
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| = \left(\frac{\mathrm d}{dt}\lvert\psi\rangle\right)\langle\psi\lvert + \lvert\psi\rangle\left(\frac{\mathrm d}{\mathrm dt}\langle\psi\lvert\right)$$ | = \left(\frac{\mathrm d}{dt}\lvert\psi\rangle\right)\langle\psi\lvert + \lvert\psi\rangle\left(\frac{\mathrm d}{\mathrm dt}\langle\psi\lvert\right)$$ | ||
| - | Now, start from the Schrodinger equation for " | + | Now, start from the Schrodinger equation for " |
| - | Recall that the Hamiltonian | + | $$ i\hbar\frac{\mathrm d}{\mathrm dt}\lvert\psi\rangle |
| - | $$i\hbar\frac{\mathrm d}{\mathrm dt}\lvert\psi\rangle | + | Move $i\hbar$ to the other side (this will be convenient later). Recall the reciprocal value of the imaginary unit flips the sign $1 / i = -i$. |
| - | \qquad | + | |
| - | Move $i\hbar$ to the right hand side. Recall the reciprocal value of the imaginary unit flips the sign $1 / i = -i$ | + | $$ \frac{\mathrm d}{\mathrm dt}\lvert\psi\rangle = -\frac{i}{\hbar}H\lvert\psi\rangle |
| + | |||
| + | Apply the Hermitian adjoint operation | ||
| $$\frac{\mathrm d}{\mathrm dt}\lvert\psi\rangle = -\frac{i}{\hbar}H\lvert\psi\rangle | $$\frac{\mathrm d}{\mathrm dt}\lvert\psi\rangle = -\frac{i}{\hbar}H\lvert\psi\rangle | ||
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| $$\frac{\mathrm d\rho}{dt} = -\frac{i}{\hbar}(H\rho - \rho H)$$ | $$\frac{\mathrm d\rho}{dt} = -\frac{i}{\hbar}(H\rho - \rho H)$$ | ||
| - | Define the commutator $[X, Y] = XY - YX$ then replace $(H\rho - \rho H) = [H, \rho]$ | + | Define the commutator $[X, Y] = XY - YX$. Then use the commutator to replace $(H\rho - \rho H)$ with $[H, \rho]$. |
| $$\frac{\mathrm d\rho}{dt} = -\frac{i}{\hbar}[H, | $$\frac{\mathrm d\rho}{dt} = -\frac{i}{\hbar}[H, | ||
| That's the von Neumann equation! | That's the von Neumann equation! | ||
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| + | ## List of code implementations | ||
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| + | - [[von-neumann-equation-qutip|von Neumann equation (QuTiP)]] | ||
von-neumann-equation.1781015909.txt.gz · Last modified: by Ivan Janevski
