RX rotates a qubit around the x-axis by angle $\theta$.
Matrix:
$$R_X(\theta) = \begin{pmatrix} \cos(\theta/2) & -i\sin(\theta/2) \\ -i\sin(\theta/2) & \cos(\theta/2) \end{pmatrix}$$
Action: $R_X(\theta)|\psi\rangle$ rotates $|\psi\rangle$ by $\theta$ radians around x-axis on Bloch sphere.
Special cases: